Emergency services including two fire services were called from Jedburgh and Hawick to the B6358 between Jedburgh and Denholm at Ruecastle Junction around 3.40pm.
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The road was closed and police say their investigations into the circumstances of the accident are still ongoing.
A Police Scotland spokesperson said: “At approximately 3.40pm on Monday, 13 March 2023, Police received a report of a two-car crash on the B6358 at Ruecastle Junction.
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“Emergency services attended and the woman was taken by ambulance to the Royal Infirmary in Edinburgh.
Investigations into the circumstances of the accident are still ongoing.”
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